Significance and Use
5.1 The presence of 4-CBA and p-TOL in PTA used for the production of polyester is undesirable because they can slow down the polymerization process; and 4-CBA is also imparting coloration to the polymer due to thermal instability.
5.2 Determining the amount of 4-CBA and p-TOL remaining from the manufacture of PTA is often required. This test method is suitable for setting specifications and for use as an internal quality control where these products are produced or used.
5.3 This test method is intended as an alternative to the HPLC method for determination of 4-CBA and p-TOL in PTA. The major benefits of CE are speed, simplicity, reduced reagent consumption and operating costs.
Scope
1.1 This test method covers the determination of 4-carboxybenzaldehyde (4-CBA) and p-toluic acid (p-TOL) in purified terephthalic acid (PTA) by capillary electrophoresis (CE) with normal voltage mode and UV detection. It is applicable for 4-CBA from 5 to 400 mg/kg and for p-TOL from 10 to 400 mg/kg, respectively.
1.2 In determining the conformance of the test results using this method to applicable specifications, results shall be rounded off in accordance with the rounding-off method of Practice E29.
1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.
1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.