Significance and Use

American National Standards Institute Inc.

5.1 Methanol and ethanol are generated by the degradation of cellulosic materials used in the solid insulation systems of electrical equipment. More particularly, methanol comes from the depolymerization of cellulosic materials.3, 4, 5, 6

5.2 Methanol and ethanol, which are soluble in an insulating liquid to an appreciable degree, will proportionally migrate to that liquid after being produced from the cellulose.

5.3 High concentrations or unusual increases in the concentrations of methanol or ethanol, or both, in an insulating liquid may indicate cellulose degradation from aging or incipient fault conditions. Testing for these alcohols may be used to complement dissolved gas-in-oil analysis and furanic compounds as performed in accordance with Test Methods D3612 and D5837 respectively.

Scope

1.1 This test method describes the determination of by-products of cellulosic materials degradation found in electrical insulation systems that are immersed in insulating liquid. Such materials include paper, pressboard, wood and cotton materials. This test method allows the analysis of methanol and ethanol from the sample matrix by headspace GC-MS or GC-FID.

1.2 This test method has been used to test for methanol and ethanol in mineral insulating liquids and less flammable electrical insulating liquids of mineral origin as defined in D3487 and D5222 respectively. Currently, this method is not a practical application for ester liquids.

1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety, health, and environmental practices and determine the applicability of regulatory limitations prior to use.

1.5 This international standard was developed in accordance with internationally recognized principles on standardization established in the Decision on Principles for the Development of International Standards, Guides and Recommendations issued by the World Trade Organization Technical Barriers to Trade (TBT) Committee.

Go to ASTM D8086 at ASTM.org

Add your thoughts about the standard.

1375 - Demolition Materials (549) 1377 - Cartridge and Propellant Actuated Devices and Components (524) 4720 - Hose and Flexible Tubing (552) 4730 - Hose, Pipe, Tube, Lubrication, and Railing Fittings (1823) 5120 - Hand Tools, Nonedged, Nonpowered (1124) 5305 - Screws (781) 5306 - Bolts (996) 5310 - Nuts and Washers (864) 5330 - Packing and Gasket Materials (583) 5340 - Hardware, Commercial (953) 5905 - Resistor (753) 5910 - Capacitors (783) 5930 - Switches (1012) 5935 - Connectors, Electrical (4357) 5940 - Lugs, Terminals, and Terminal Strips (564) 5945 - Relays and Solenoids (733) 5950 - Coils and Transformers (856) 5960 - Electron Tubes and Associated Hardware (1630) 5961 - Semiconductor Devices and Associated Hardware (707) 6145 - Wire and Cable, Electrical (1629) 6240 - Electric Lamps (662) 6505 - Drugs and Biologicals (1343) 6515 - Medical and Surgical Instruments, Equipment, and Supplies (1907) 6520 - Dental Instruments, Equipment, and Supplies (790) 6530 - Hospital Furniture, Equipment, Utensils, and Supplies (745) 6610 - Flight Instruments (540) 6625 - Electrical and Electronic Properties Measuring and Testing Instruments (1241) 6640 - Laboratory Equipment and Supplies (1187) 6810 - Chemicals (1114) 8010 - Paints, Dopes, Varnishes, and Related Products (2046) 8030 - Preservative and Sealing Compounds (554) 8140 - Ammunition and Nuclear Ordnance Boxes, Packages and Special Containers (797) 8305 - Textile Fabrics (910) 8415 - Clothing, Special Purpose (660) 8455 - Badges and Insignia (3093) 8915 - Fruits and Vegetables (531) 9330 - Plastics Fabricated Materials (759) FACR (1647) ISDA (1776) ISDD (786) ISDF (1827) ISDN (581) MISC (1045) PACK (539) SESS (581)
Aerospace Material (225) Aircraft Air Conditioning, Heating, and Pressurizing Equipment (334) Aircraft Hydraulic, Vacuum, and De-icing System Components (263) Ammunition, 75mm through 125mm (192) Ammunition, over 30mm up to 75mm (208) Ammunition, through 30mm (349) Analytical Chemistry (180) Bombs (192) Building (414) Bulk Explosives (261) Cartridge and Propellant Actuated Devices and Components (524) Consumer Product Evaluation (267) Copper (192) Demolition Materials (549) Electrical and Magnetic Conductor (162) Electronics (153) Environmental Toxicology (187) Fire Control Computing Sights and Devices (338) Fire Control Radar Equipment, except Airborne (197) Fuzes and Primers (454) Geotechnical Engineering (217) GUN (640) Land Mines (276) Medical Device and Implant (427) Military Chemical Agents (156) Miscellaneous Aircraft Accessories and Components (231) Miscellaneous Fire Control Equipment (216) Nondestructive Testing (246) Nonferrous Metal and Nonferrous Alloy (367) Nuclear Technology (274) Optical Sighting and Ranging Equipment (451) Paint and Related Coating (456) Parachutes; Aerial Pick Up, Delivery, Recovery Systems; and Cargo Tie Down Equipment (324) Petroleum (378) Plastic Pipe (248) Pyrotechnics (175) Road and Paving (177) Rockets, Rocket Ammunition and Rocket Components (368) Rubber (166) Security System Pedestrian and Walkway Safety (157) Specialized Test and Handling Equipment, Nuclear Ordnance (150) Sports and Recreation (316) Steel (908) Torpedos and Components, Inert (258) (621)